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Iron Catalysis In Organic Chemistry By Bernd Plietker

Iron Catalysis In Organic Chemistry By Bernd Plietker

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Bernd Plietker

Over the past two decades, sustainability has become a cornerstone in conversations across politics, society, and science. The pressing challenge of our time is to produce high-quality goods while minimizing waste and reducing energy consumption. This issue becomes even more critical when we factor in the growing global population and dwindling fossil fuel reserves.

In the realm of chemistry, sustainability is defined through efficient, low-waste chemical processes and the strategic use of catalysts to lower energy demands. While many catalytic reactions align with the principles of sustainable transformation at a broader scale, they often fall short on a deeper level. The high cost of catalysts—usually based on transition metals—and their ligands, along with their inherent toxicity, can undermine the very criteria they aim to meet.

Preface

Page XI

List of Contributors
Page XIII

1. Iron Complexes in Organic Chemistry

By: Ingmar Bauer and Hans-Joachim Knölker
Page: 1
Explore the fascinating role of iron complexes and their transformative impact on organic chemistry.


2. Iron Catalysis in Biological and Biomimetic Reactions

Page: 29
Dive into how iron catalysis mirrors nature’s processes, bridging biological and synthetic chemistry with elegance.


3. Iron-Catalyzed Oxidation Reactions

Page: 73
Uncover the power of iron in driving efficient oxidation reactions, a cornerstone in modern chemistry.


4. Reduction of Unsaturated Compounds with Homogeneous Iron Catalysts

By: Stephan Enthaler, Kathrin Junge, and Matthias Beller
Page: 125
Learn how unsaturated compounds are transformed using homogeneous iron catalysts, showcasing their efficiency and versatility.


5. Iron-Catalyzed Cross-Coupling Reactions

By: Andreas Leitner
Page: 147
Discover the groundbreaking advances in cross-coupling reactions enabled by iron catalysts, pushing the boundaries of synthetic chemistry.


6. Iron-Catalyzed Aromatic Substitutions

By: Jette Kischel, Kristin Mertins, Irina Jovel, Alexander Zapf, and Matthias Beller
Page: 177
Delve into the art of aromatic substitutions, where iron takes center stage in precise and innovative transformations.


7. Iron-Catalyzed Substitution Reactions

By: Bernd Plietker
Page: 197
Explore the versatile world of substitution reactions, made more sustainable and efficient with iron catalysis.


8. Addition and Conjugate Addition Reactions to Carbonyl Compounds

By: Jens Christoffers, Herbert Frey, and Anna Rosiak
Page: 217
Understand how iron catalysts enable the seamless addition to carbonyl compounds, redefining chemical synthesis.


9. Iron-Catalyzed Cycloadditions and Ring Expansion Reactions

By: Gerhard Hilt and Judith Janikowski
Page: 245
Step into the realm of cycloadditions and ring expansions, where iron catalysis unlocks new synthetic possibilities.


Index
Page: 271

File Details:
Size: 2.55 MB
Total Pages: 297

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